I have an Identity defined and separate settings for the folder for 'sent mail'. When this Identity receives an inviation for calendar, the reply is not stored in the defined folder for this identity, but in 'local folders/sendmail' -> setting in the identity for send mail is ignored
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Issue still persists in KMail 5.21.2
Same problem occurs when replying to an invitation (calendar event): KMail displays the correct persona, but picks a wrong delivery method. And in fact it does not evaluate the settings of the persona, as - message fails to send (delivery methond) - error message 'No folder for send messages found' when opening the non-sent mail in the outbox